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Default Configuration

cat /etc/postfix/main.cf | grep -v "#" | sed -r "/^|s*$/d"

Command Description
AUTH PLAIN AUTH is a service extension used to authenticate the client.
HELO The client logs in with its computer name and thus starts the session.
MAIL FROM The client names the email sender.
RCPT TO The client names the email recipient.
DATA The client initiates the transmission of the email.
RSET The client aborts the initiated transmission but keeps the connection between client and server.
VRFY The client checks if a mailbox is available for message transfer.
EXPN The client also checks if a mailbox is available for messaging with this command.
NOOP The client requests a response from the server to prevent disconnection due to time-out.
QUIT The client terminates the session.

Telnet - HELO/EHLO

You can use the telnet tool to connect to an SMTP server and start the session by typing the commands HELO or EHLO. telnet 10.129.14.128 25

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https://serversmtp.com/smtp-error/

Telnet - VRFY