effect of temperature

Reaction:

Sodium thiosulfate + hydrochloric acid → sulfur + sulfur dioxide + water

RQ: How does the temperature of sodium thiosulfate solution affect the rate of reaction with hydrochloric acid?

Hypothesis: Increasing temperature will increase the rate of reaction (time for X to disappear will decrease) because particles have greater kinetic energy so more collisions exceed Ea.


Variables:

IV: Temperature of sodium thiosulfate solution (e.g., 15, 25, 35, 45 °C)

DV: Time (s) for cross to disappear (or Rate = 1/time)

CVs: Concentration of reagents, volumes used, total reaction vessel size, same observer, same black X, ambient light, stirring (none)


Apparatus

Equipment Size/Specification Quantity
Conical flask 100 cm³ 1
Measuring cylinder 50cm³ 1
Measuring cylinder 10cm³ 1
Thermometer - 1
Stopwatch - 1
Water bath / beakers 250 cm³ 1
Sodium thiosulfate solution 0.10 mol 25 cm³ per trial
Hydrochloric acid 1.0 mol 5 cm³ per trial
White card with black “X” - 1

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Risk Assessment:

Hazard Risk Precaution
Hydrochloric acid Corrosive and causes irritation Wear goggles, gloves and lab coat
Hot water in bath Causes burns Wear goggles, gloves and lab coat
Sulfur dioxide (from reaction) Causes respiratory irritation Use in well-ventilated area or fume cupboard
Glassware Causes cuts and scrapes Wear goggles, gloves and lab coat

Method:

  1. Measure out 50 cm³ of sodium thiosulfate solution and pour it into a conical flask.
  2. Draw a black cross (X) on a piece of white paper and place the flask directly on top of it.